I am not exactly sure what you mean by 'surface' in a slice, but I will give you two options and hopefully one of them is what you are looking for.
1) Isosurfaces of Soot Density, In the PyroSim 'Output' menu, there is an 'Isosurfaces...' option. In the 'Animated Isosurfaces' dialog scroll down until you see the row with the Quantity of '[Extra Species: soot] Density', click the checkbox to the left of this quantity. Then, in the contour values cell next to the Quantity label, enter '4.0E-5' (don't add the quotes). This will instruct FDS to create an isosurface where the soot density is at 40 mg/m^3 (0.00004 kg/m^3). This will not be indicated just on the slice contour, but will show this bounding surface throughout the domain. If you want to add another isosurface at a higher concentration, let's say at 50mg/m^3, then in the Contour Values cell you should enter '4.0E-5; 5.0E-5' with the values separated by a semi-colon. You can add as many values as you want to this cell, and each value will be represented by a different isosurface in smokeview.
To see the isosurfaces in Smokeview, just Load the Isosurface data and watch it animate over time.
2) Indicate on a slice plane where a certain value is located. To do this, load the slice for soot density, and then click in the color-bar to the right. You will see that where you clicked will turn black and a value will be indicated next to it. Click and drag the black mark up or down the color-bar until the value next to it is 0.04 (*10^-3). You will see in the slice black everywhere that the concentration is 40 mg/m^3.
I have attached a couple of images showing the Soot Density slice with the 0.04 values marked in black. Then with the isosurface (magenta) and the slice marked in black so that you can see that the isosurface intersects the slice contour where the black color is marked. And a final image looking down the plume, showing that the isosurface only marks where the concentration is as indicated in the Contour Values cell. Think of the isosurface as an animated boundary where everything outside of it is less than the value, and everything inside of it is greater than the value, and in this case the value is 40 mg/m^3.
I hope this helps,
-Bryan Klein